The [2+2] cycloaddition is a versatile strategy for the synthesis of strained cyclobutenes of high synthetic value. In this study, two efficient intermolecular [2+2] cycloadditions between two different types of chloroalkynes and unactivated alkene are realized with gold catalysis. Of significance is that the reaction works with challenging monosubstituted unactivated alkenes,
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The formation of a complex between two species such as a protein and a ligand, is an example of the very common two-reactant, or bimolecular, reaction. Although many important complexes in biochemistry contain multiple components, these will almost invariably be assembled through a series of individual reactions with just two reactants.
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